Volume 9, Issue 1 (Winter 2020)                   Arch Hyg Sci 2020, 9(1): 48-57 | Back to browse issues page


XML Print


Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:

Shokri A, Karimi S. Treatment of Aqueous Solution Containing Acid red 14 using an Electro Peroxone Process and a Box-Behnken Experimental Design. Arch Hyg Sci 2020; 9 (1) :48-57
URL: http://jhygiene.muq.ac.ir/article-1-431-en.html
1- Department of Chemistry, Payame Noor University, Tehran, Iran
2- Department of Chemical Engineering, Jundi-Shapur University of Technology, Jundi-Shapur research institute, Dezful, Iran
Abstract:   (4007 Views)
Background & Aims of the Study: Azo dyes utilized in industrial processes, such as the textile manufacturing, lead to the creation of huge amounts of colored wastewaters that contain non-organic and organic constituents. Therefore, it is necessary to search for remedies in this regard. This study investigated the degradation and mineralization of Acid red 14 (AR14), which is a mono Azo dye generally employed in textile manufacturing, using an Electro peroxone process. The Electro-peroxone is a grouping of ozone and electrochemically generated hydrogen peroxide that can result in the production of strong hydroxyl radicals.
Materials and Methods: This project was accompanied on synthetic wastewater that holds a high concentration of Acid red 14(400 mg/l) based on a Box-Behnken experimental design using an Electro-peroxone process for the remediation. Moreover, the influence of operational parameters was investigated in this study.
Results: The results obtained from an Electro-peroxone process in a cylinder-shaped reactor showed 100% AR14 removal after 30 min with an initial dosage of dye  at 400 mg/l at an optimum condition (current intensity at 0.7 A, pH at 10, reaction time at 30 min, and electrolyte concentration at 0.1 M). Moreover, the removal percentage of the chemical oxygen demand was obtained at 69% after 30 min indicating the great performance of Electro-peroxone in the mineralization of AR14.
Conclusion: The hydrogen peroxide is produced electrochemically from O2 in the O2-O3 mixture, which was entered into the reactor. Subsequently, the hydroxyl radicals were shaped via the peroxone reaction. Based on the high removal percentages of COD in short reaction time, it can be found that the Electro-peroxone process produces no secondary pollutants. Therefore, it can be regarded as an environmentally-friendly water treatment method.
Full-Text [PDF 798 kb]   (757 Downloads) |   |   Full-Text (HTML)  (961 Views)  
Type of Study: Original Article | Subject: Environmental Health
Received: 2019/12/7 | Accepted: 2020/01/20 | Published: 2020/03/29

References
1. 1. Shokri A. Employing electrocoagulation for the removal of Acid Red 182 in aqueous environment by using Box-Behnken design method. Desal Water Treat 2018; 115:281-287. [DOI:10.5004/dwt.2018.22451]
2. Shokri A. Removal of Acid red 33 from aqueous solution by Fenton and photo Fenton processes. J Chem Health Risk. 2017; 7(2), 119-131.
3. Asadi F, Dargahi A, Almasi Ali, Moghofe E. Red Reactive 2 Dye Removal from Aqueous Solutions by Pumice as a Low-Cost and Available Adsorbent. Arch Hyg Sci 2016; 5(3): 145-52.
4. Shokri A. Kazem Mahanpoor, Degradation of Ortho-Toluidine from aqueous solution by the TiO2/O3 process. Int J Ind Chem 2017; 8:101-108. [DOI:10.1007/s40090-016-0110-z]
5. Shokri A, Mahanpoor K, Soodbar D. Degradation of 2-Nitrophenol from Petrochemical Wastewater by UV/NiFe2O4/Clinoptilolite process. Fresen Environ Bull 2016; 25: 500-508.
6. Shokri A, Ali Hassani Joshaghani. Using microwave along with TiO2 for the degradation of 4-Chloro- 2-Nitro phenol in aqueous environment. Rus J Appl Chem 2016; 89:1985-1990. [DOI:10.1134/S1070427216120090]
7. Shokri A, Mahanpoor K, Soodbar D. Degradation of Ortho-Toluidine in petrochemical wastewater by ozonation,UV/O3, O3/H2O2 and UV/O3/H2O2 processes. Des Water Treat 2016; 57:16473-16482. [DOI:10.1080/19443994.2015.1085454]
8. Shokri A. Degradation of 2-Nitrophenol from Petrochemical Wastewater by Ozone. Rus J Appl Chem 2015; 88: 2038−2043. [DOI:10.1134/S10704272150120216]
9. Bakheet B, Yuan S, Li Z, Wang H, Zuo J, Komarneni S, Wang Y. Electro-peroxone treatment of Orange II dye wastewater. Water Res 47; 2013: 6234-6243. [DOI:10.1016/j.watres.2013.07.042]
10. Wang H, Bakheet B, Yuan S, Li X, Yu G, Murayama S, Wang Y. Kinetics and energy efficiency for the degradation of 1,4-dioxane by Electro-peroxone process. J Hazard Mater 2015; 294: 90-98. [DOI:10.1016/j.jhazmat.2015.03.058]
11. Hsing HJ. Chiang PC, Chang EE, Chen MY. The decolorization and mineralization of Acid Orange 6 azo dye in aqueous solution by advanced oxidation processes: a comparative study. J Hazard Mater 2007; 141 (1): 8-16. [DOI:10.1016/j.jhazmat.2006.05.122]
12. Pocostales JP, Sein MM, Knolle W, Von Sonntag C, Schmidt TC. Degradation of ozone-refractory organic phosphates in wastewater by ozone and ozone/hydrogen peroxide (peroxone): the role of ozone consumption by dissolved organic matter. Environ Sci & Technol 2010; 44 (21): 8248-8253. [DOI:10.1021/es1018288]
13. Xu AH, Li XX, Ye SA, Yin GC, Zeng QF. Catalyzed oxidative degradation of methylene blue by in situ generated cobalt (II)-bicarbonate complexes with hydrogen peroxide. Appl Catal B: Environ 2011;102 (1-2): 37-43. [DOI:10.1016/j.apcatb.2010.11.022]
14. Shokri A. Application of Sonocatalyst and Sonophotocatalyst for Degradation of Acid Red 14 in Aqueous Environment. Arch Hyg Sci 2016; 5(4): 229-235.
15. Wang YJ, Li X, Zhen L, Zhang H, Zhang Y, Wang C. Electro-fenton treatment of concentrates generated in nanofiltration of biologically pretreated landfill leachate. J Hazard Mater 2012; 229-230:115-121. [DOI:10.1016/j.jhazmat.2012.05.108]
16. Kolthof IM, Sandell EB, Meeehan EJ, Buckstein S. Quantitative Chemical Analysis, 4thed., Macmillan, New York, 1862-1867.
17. Shokri A. Degradation of 2-Nitrophenol from Petrochemical Wastewater by Ozone, Russ. J. Appl. Chem., 2015; 88:2038−2043. [DOI:10.1134/S10704272150120216]
18. Mohadesi M, Shokri A. Evaluation of Fenton and photo-Fenton processes for the removal of p-chloronitrobenzene in aqueous environment using Box-Behnken design method. Desal Water Treat 2017; 81: 199-208. [DOI:10.5004/dwt.2017.21182]
19. Shokri A, Bayat A, Mahanpoor K. Employing Fenton-like process for the remediation of petrochemical wastewater through Box-Behnken design method. Desal Water Treat 2019; 166: 135-143. [DOI:10.5004/dwt.2019.24634]
20. Khataee AR, Safarpour M, Zarei M, Aber S. Electrochemical generation of H2O2 using immobilized carbon nanotubes on graphite electrode fed with air: investigation of operational parameters. J Electroanal Chem 2011; 659: 63-68. [DOI:10.1016/j.jelechem.2011.05.002]
21. Li X, Wang Y, Yuan S, Li Z, Wang B, Huang J, Deng S, Yu G, Degradation of the anti-inflammatory drug ibuprofen by Electro-peroxone process. Water Res 2014; 63: 81-93. [DOI:10.1016/j.watres.2014.06.009]
22. Li Y, Shen W, Fu S, Yang H, Yu G, Wang Y. Inhibition of bromate formation during drinking water treatment by adapting ozonation to Electro-peroxone process. Chem Eng J 2015; 264: 322-328. [DOI:10.1016/j.cej.2014.11.120]
23. Daneshvar N, Aber S, Vatanpour V, Rasoulifard MH. Electro-Fenton treatment of dye solution containing Orange II: influence of operational parameters. J Electroanal Chem 2008; 615: 165-174. [DOI:10.1016/j.jelechem.2007.12.005]
24. Wu D, Lu G, Zhang R, Lin Q, Yao J, Shen X, Wang W. Effective degradation of diatrizoate by Electro-peroxone process using ferrite/carbon nanotubes based gas diffusion cathode. Electrochim Acta 2017; 236: 297-306. [DOI:10.1016/j.electacta.2017.03.196]
25. Yuan S, Li Z, Wang Y. Effective degradation of methylene blue by a novel electrochemically driven process. Electrochem Commun 2013; 29:48-51. [DOI:10.1016/j.elecom.2013.01.012]
26. Brillas E, Sires I, Oturan MA. Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry. Chem Rev 2009; 109(12): 6570-6631. [DOI:10.1021/cr900136g]
27. Wang H, Zhan J, Yao W, Wang B, Deng S, Huang J, Yu G, Wang Y. Comparison of pharmaceutical abatement in various water matrices by conventional ozonation, peroxone (O3/H2O2), and an Electro-peroxone process. Water Res 2018; 130: 127-138. [DOI:10.1016/j.watres.2017.11.054]
28. Khataee AR, Safarpour M, Zarei M, Aber S. Electrochemical generation of H2O2 using immobilized carbon nanotubes on graphite electrode fed with air: investigation of operational parameters. J Electroanal Chem 2011; 659: 63-68. [DOI:10.1016/j.jelechem.2011.05.002]

Add your comments about this article : Your username or Email:
CAPTCHA

Send email to the article author


Rights and permissions
Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

© 2025 CC BY-NC 4.0 | Archives of Hygiene Sciences

Designed & Developed by : Yektaweb