Volume 6, Issue 4 (Autumn 2017)                   Arch Hyg Sci 2017, 6(4): 370-376 | Back to browse issues page


XML Print


Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:

Samarghandi M R, Rahmani A, Asgarai G, Dargahi A, Ahmadidoost G. Photocatalytic Role of Zinc Oxide Nanoparticles on Synthetic Activated Carbon to Remove Antibiotic from Aquatic Environment. Arch Hyg Sci 2017; 6 (4) :370-376
URL: http://jhygiene.muq.ac.ir/article-1-277-en.html
1- Department of Environmental Health Engineering, School of Health, Hamadan University of Medical Sciences, Hamadan, Iran.
2- Department of environmental health engineering, School of Health, Hamadan University of Medical Sciences, Hamadan, Iran.
3- Department of Environmental Health Engineering, School of Health, Ardabil University of Medical Sciences, Ardabil, Iran
Abstract:   (4791 Views)
Background & Aims of the Study: The presence of antibiotics in the environment, especially in aquatic environments is a major concern for health and the environment. The advanced oxidation process due to the ease of use, economical advantages and high performance have attracted a lot of attention. The purpose of this study was Evaluating of the photocatalytic role of zinc oxide on synthetic activated carbon to remove antibiotic from aquatic environment.
Materials & Methods: This experimental study was done in batch reactor that has a 1 L volume. In this study effect of parameters such as initial pH (3-9), initial concentration of cefazolin (20-200 mg/L), modified photocatalyst concentration (20-100 mg/L) and reaction time (10-60 min) was investigated. In this study a low-pressure mercury lamp with the power of 55 watts in stainless case has been used. The cefazolin concentrations in different steps were measured using UV-Vis spectrophotometer in Wavelength of 262 nm.
Results: The results showed that the highest removal efficiency (96%) of cefazolin was at the pH=3, 0.1 mg/L of modified photocatalyst, retention time of 60 min and cefazolin concentrations of 100 mg/L. In the case of changing any of the above mentioned values, process efficiency was decreased.
Conclusion: The results showed that the photocatalytic process of zinc oxide nanoparticles on synthetic activated carbon can be used as an advanced oxidation process to effectively remove pollutants like cefazolin and other similar pollutants.
Full-Text [PDF 764 kb]   (1238 Downloads) |   |   Full-Text (HTML)  (9813 Views)  
Type of Study: Original Article | Subject: Environmental Health
Received: 2017/07/17 | Accepted: 2017/09/10 | Published: 2017/09/30

References
1. 1. Neisi A, Mohammadi MJ, Takdastan A, Babaeie AA, Yari AR, Farhadi M. Assessment of tetracycline antibiotic removal from hospital wastewater by extended aeration activated sludge. Desalination Water Treat. 2017;80:380-386. [DOI:10.5004/dwt.2017.20935]
2. Shokoohi R, Leili M, Dargahi A, Vaziri Y, Khamutian R. Common Antibiotics in Wastewater of Sina and Besat Hospitals, Hamadan, Iran. Arch Hyg Sci 2017;6(2):152-159. [DOI:10.29252/ArchHygSci.6.2.152]
3. Azizi E, Ghayebzadeh M, Dargahi A, Hemati L, Beikmohammadi M, Sharafi K. Determination of Effective Parameters on Removal of Organic Materials from Pharmaceutical Industry Wastewater by Advanced Oxidation Process (H2O2/UV). Arch Hyg Sci 2016;5(2):69-74.
4. Gu C, Karthikeyan KG, Sibley SD, Pedersen JA. Complexation of the antibiotic tetracycline with humic acid. Chemosphere 2007;66(8):1494-501. [DOI:10.1016/j.chemosphere.2006.08.028]
5. Wei R, Ge F, Huang S, Chen M, Wang R. Occurrence of veterinary antibiotics in animal wastewater and surface water around farms in Jiangsu Province, China. Chemosphere 2011;82(10):1408-14. [DOI:10.1016/j.chemosphere.2010.11.067]
6. Guo X, Feng C, Zhang J, Tian C, Liu J. Role of dams in the phase transfer of antibiotics in an urban river receiving wastewater treatment plant effluent. Sci Total Environ 607-608 (2017) 1173-9. [DOI:10.1016/j.scitotenv.2017.07.096]
7. Andreozzi R, Campanella L, Fraysse B, Garric J, Gonnella A, Lo Giudice R, et al. Effects of advanced oxidation processes (AOPs) on the toxicity of a mixture of pharmaceuticals. Water Sci Techno 2004;50(5):23-8. [DOI:10.2166/wst.2004.0304]
8. Kümmerer K. Antibiotics in the aquatic environment - A review - Part I. Chemosphere 2009;75(4):417-34. [DOI:10.1016/j.chemosphere.2008.11.086]
9. Gurkan YY, Turkten N, Hatipoglu A, Cinar Z. Photocatalytic degradation of cefazolin over N-doped TiO2 under UV and sunlight irradiation: Prediction of the reaction paths via conceptual DFT. Chem Eng J 2012;184:113-24. [DOI:10.1016/j.cej.2012.01.011]
10. Almasi A, Dargahi A, Mohamadi M, Biglari H, Amirian F, Raei M. Removal of Penicillin G by combination of sonolysis and Photocatalytic (sonophotocatalytic) process from aqueous solution: process optimization using RSM (Response Surface Methodology). Electronic physician 2016;8(9):2878. [DOI:10.19082/2878]
11. Shokri M, Isapour G, Behnajady MA, Dorosti S. A comparative study of photocatalytic degradation of the antibiotic cefazolin by suspended and immobilized TiO2nanoparticles. Desalination Water Treat 2015;57(27):12874-81. [DOI:10.1080/19443994.2015.1053534]
12. Zhang J, Meng J, Li Y, Hu C. Investigation of the Toxic Functional Group of Cephalosporins by Zebrafish Embryo Toxicity Test. Arch Pharm (Weinheim) 2010;343(10):553-60. [DOI:10.1002/ardp.201000005]
13. Ahmad AA, Hameed BH. Fixed-bed adsorption of reactive azo dye onto granular activated carbon prepared from waste. J Hazard Mater 2010;175(1-3):298-303. [DOI:10.1016/j.jhazmat.2009.10.003]
14. Fen L, Bo Y, Wei J, Zhenlong G. Preparation of Activated Carbon Loading Nano-ZnO and Desulfurization Properties under Room Temperature. In: Zhang W, editor. Software Engineering and Knowledge Engineering: Theory and Practice: Selected papers from 2012 International Conference on Software Engineering, Knowledge Engineering and Information Engineering (SEKEIE 2012). Berlin, Heidelberg: Springer Berlin Heidelberg; 2012. p. 177-83. [DOI:10.1007/978-3-642-29455-6_26]
15. Kumar H, Rani R. Structural and Optical Characterization of ZnO Nanoparticles Synthesized by Microemulsion Route. Int Letters Chem Phys Astron 2013;14:26-36. [DOI:10.18052/www.scipress.com/ILCPA.19.26]
16. Muruganandham M, Swaminathan M. Decolourisation of Reactive Orange 4 by Fenton and photo-Fenton oxidation technology. Dyes Pigm 2004;63(3):315-21. [DOI:10.1016/j.dyepig.2004.03.004]
17. Muthirulan P, Meenakshisundararam M, Kannan N. Beneficial role of ZnO photocatalyst supported with porous activated carbon for the mineralization of alizarin cyanin green dye in aqueous solution. J Adv Res 2013;4(6):479-84. [DOI:10.1016/j.jare.2012.08.005]
18. Samarghandi MR, Siboni M, Maleki A, Jafari SJ, Nazemi F. Kinetic Determination and Efficiency of Titanium Dioxide Photocatalytic Process in Removal of Reactive Black 5 (RB5) Dye and Cyanide from Aquatic Solution. J Mazandaran Univ Med Sci 2011;21(81):44-52.
19. Daneshvar N, Aber S, Seyed Dorraji MS, Khataee AR, Rasoulifard MH. Photocatalytic degradation of the insecticide diazinon in the presence of prepared nanocrystalline ZnO powders under irradiation of UV-C light. Sep Purif Technol 2007;58(1):91-8. [DOI:10.1016/j.seppur.2007.07.016]

Add your comments about this article : Your username or Email:
CAPTCHA

Send email to the article author


Rights and permissions
Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

© 2025 CC BY-NC 4.0 | Archives of Hygiene Sciences

Designed & Developed by : Yektaweb