Degradation of Acid Orange 7 Dye with PMS and H2O2 Activated by CoFe2O4/PAC Nanocomposite

Esmaeili, Shirin; Dehvari, Mahboobeh; Babaei, AliAkbar

doi:10.29252/ArchHygSci.8.1.35

Volume 8, Issue 1 (Winter 2019) Arch Hyg Sci 2019, 8(1): 35-45 | Back to browse issues page

‎ 10.29252/ArchHygSci.8.1.35

‎ 20.1001.1.22519203.2019.8.1.8.8

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Esmaeili S, Dehvari M, Babaei A. Degradation of Acid Orange 7 Dye with PMS and H2O2 Activated by CoFe2O4/PAC Nanocomposite. Arch Hyg Sci 2019; 8 (1) :35-45
URL: http://jhygiene.muq.ac.ir/article-1-379-en.html

Degradation of Acid Orange 7 Dye with PMS and H2O2 Activated by CoFe2O4/PAC Nanocomposite

Shirin Esmaeili¹

, Mahboobeh Dehvari¹

, AliAkbar Babaei ^*

1- Department of environmental health engineering, School of Health, Ahvaz Joundishapour University of medical sciences, Ahvaz, Iran

Abstract: (4164 Views)

Background & Aims of the Study: Discharge of untreated colored wastewater into aquatic environments could cause problems such as cancer. Among the various treatment methods, advanced oxidation processes (AOPs) have attracted much attention in recent years. The aim of this study was the removal of acid orange 7 dye using CoFe₂O₄@PAC nanocomposite in the presence of peroxymonosulfate (PMS) and hydrogen peroxide (H₂O₂).
Materials & Methods: The various variables effect including pH, catalyst dose, peroxymonosulfate and hydrogen peroxide concentration, reaction time, and initial dye concentration were evaluated. The synthesized nanocomposite was characterized by SEM, EDX, XRD and BET analyses. The residual concentration of AO7 dye was determined using UV–Vis spectrophotometer at wavelength of 485 nm.
Results: It was found that decolorization increases by increasing the catalyst dosage and reaction time, and decreasing pH. With increasing the dye initial concentration from 10 mg/L to 250 mg/L, in the presence of H₂O₂ and PMS dye removal decreased from 99.5% to 39.7% and from 99.9% to 43.7%, respectively. The adsorption kinetics was found to follow pseudo-first-order kinetic model (R²>0.99).
Conclusions: The results indicated that the prepared composite could be used as an effective and environmental friendly magnetic adsorbent for the removal of AO7 dye from aqueous solutions.

Keywords: Acid Orange 7 dye, Degradation efficiency, nanocomposite, PMS, H2O2

Full-Text [PDF 597 kb] (1059 Downloads) | | Full-Text (HTML) (921 Views)

Type of Study: Original Article | Subject: Environmental Health
Received: 2017/09/13 | Accepted: 2019/02/28 | Published: 2019/05/28

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